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I do quite a bit of cleaning with white vinegar. It's great for removing hard water stains in the kitchen and bathroom areas.
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Baking soda and lemons in addition to vinegar. I mean not all at the same time. Try one of the three.
We use soapnuts to wash batik. Soapnuts are fruits of a tree scintifically called Sapindus. The fruit also gives other benefits besides used as soap.
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