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What are Acids?

Updated on March 13, 2013

The pH Scale

The pH scale is a measure of how acidic or basic a substance is. Samples with a pH of less than 7 are acidic, samples with a pH of 7 are neutral, samples with a pH of above 7 are basic.
The pH scale is a measure of how acidic or basic a substance is. Samples with a pH of less than 7 are acidic, samples with a pH of 7 are neutral, samples with a pH of above 7 are basic. | Source

Acids and Bases - Why are Acids Acidic?

We may not give acids and bases much thought in our daily lives, but they play a huge role in our daily lives. Plants need the correct pH to grow properly, acid rain can devastate entire ecosystems, and most of our synthetic fertilisers are made through neutralisation reactions between acids and bases. But what makes one thing acidic and another thing basic? And why are these substances so dangerous?

There are many ways to define acids and bases:

  1. An acid turns blue litmus paper red; a base turns red litmus paper blue
  2. An acid is a substance with a pH of less than 7; a base is a substance with a pH greater than 7
  3. An acid contains free hydrogen ions (H+); a base contains free hydroxide ions (OH-)
  4. An acid is a proton (H+) donor; a base is a proton acceptor

All of the above definitions are true, to a greater or lesser extent, but it is the last one that makes them dangerous. Hydrogen ions (also called protons) are constantly looking to balance out their positive charge, which makes them very reactive.

Certain concentrated acids (and some concentrated bases) are so reactive they can damage other materials, including living tissue. Acids that can damage the skin are called 'corrosive;' Bases that can damage the skin are called 'caustic'*

*The mechanisms by which acids and bases damage the skin are different, so scientists describe with different words.

What is the Difference Between a Base and an Alkali

Most pupils I teach are familiar with the term acid, but give it's opposite as 'alkali.' Whilst it is true that alkalis have a pH greater than 7, contain hydroxide ions and accept protons, there are plenty of substances that are not alkali that do the same.

An alkali is a soluble base - it is a base that dissolves readily in water. Make sure to remember:

  • The opposite of an acid is a base;
  • A base that dissolves in water is known as an alkali;
  • All alkalis are bases, but not all bases are alkali.

How to Measure pH - Make Red Cabbage Indicator!

What does pH mean?

Often, the term pH is used to say how strong an acid or alkali is. pH actually has nothing to do with whether an acid is strong or weak. The letters 'pH' stand for power of hydrogen! The scale tells us the concentration of hydrogen ions in the solution.

  • At pH 0, there are lots of hydrogen ions - the solution is very acidic
  • at pH 7, there are equal numbers of hydrogen ions and hydroxide ions - the solution is neutral
  • At pH 14, there are lots of hydroxide ions - the solution is very basic (Alkaline if it dissolves in water)

pH Scale Examples

pH
Substance
Information
0
Hydrofluoric Acid
Highly corrosive. Acts as a catalyst in oil refining
1
Sulphuric Acid
Used in the production of fertilisers. Also found in acid rain
2
Lemon Juice
Contains around 5% citric acid, a weak acid which gives lemons their sour taste
3
Cola drink
Contains phosphoric acid
4
Beer
The Carbon dioxide bubbles lower the pH of beer slightly
5
Black Coffee
The acidity of coffee depends on the altitude at which the coffee beans were grown
6
Cow's milk
Cow's milk sours due to bacteria producing lactic acid
7
Distilled Water
When the number of positive and negative ions balance, you get neutral pH. Most water contains low levels of ions so is not neutral.
8
Baking Soda
A gentle cleaning product due to it's slightly raised pH
9
Toothpaste
Acid can damage tooth enamel, so a slight base is added to regulate the pH
10
Milk of Magnesia
Neutralises excess acid in the stomach
11
Ammonia
Used in many cleaning products, as well as the production of fertilisers
12
Bleach
Contains sodium hypochlorite to help break down those tough stains
13
Heavy Duty Oven Cleaner
These need to be very caustic to break down thick grease and fat
14
Sodium Hydroxide
Also known as Caustic Soda
An acid donates hydrogen ions when in solution. The higher the concentration of hydrogen ions released, the stronger the acid. Bases accept hydrogen ions in solution. They also contain ions of the opposite charge, such as hydroxide ions.

Strong Acids and Bases

So if pH has nothing to do with how strong an acid or base is, what makes an acid strong or weak?

We already know that acids form hydrogen ions when in water, and that they 'donate' these ions. This is known as ionisation. The strength of an acid depends on how well it ionises:

Strong Acids (E.g. Hydrochloric Acid)

Strong acids completely ionise in water
Strong acid → Hydrogen Ions + other ions

There are lots of hydrogen ions and very few acid molecules (remember it is the hydrogen ion that makes an acid reactive). In strong acids, the H+ ion concentration is higher and the collision frequency greater

Weak Acids (E.g. Ethanoic Acid)

Weak acids only partially ionise in water. The set up a reversible reaction
Weak acidhydrogen ions + other ions

An equilibrium mixture is formed with lots of acid molecules, but not many hydrogen ions. In weak acids the H+ ion concentration is lower and so the collision frequency is lower.

Remember! The strength of an acid or base is down to how well it ionises (how easily the hydrogen or hydroxide ions dissociate from the rest of the acid molecule), not it's pH

The Power of Sulphuric Acid

Comments

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    • yograj yog profile image

      Yogesh Oza 

      3 years ago from Ahmedabad, Gujarat, INDIA.

      This is very useful hub. Particularly, the knowledge gained by this hub on "strong acids and weak acids" is really useful. Thanks for giving a high quality information.

    • susi10 profile image

      Susan W 

      4 years ago from The British Isles, Europe

      This is a fantastic hub, Rhys and it explains everything there is to know about acids and bases beautifully. I'll be linking this to one of my acids and bases hubs, and I'll vote for it to be Editor's Choice. Well done, voted up and shared!

    • TFScientist profile imageAUTHOR

      Rhys Baker 

      5 years ago from Peterborough, UK

      One of the misconceptions I have to address early on is that bases aren't dangerous-they are often more corrosive than acids. Kids are shocked when I tell them that something can burn their skin and is NOT an acid. Thanks for your comment, MsLizzy, as always I enjoy reading your personal viewpoint.

    • DzyMsLizzy profile image

      Liz Elias 

      5 years ago from Oakley, CA

      Most fascinating! As a kid, I always wanted a chemistry set...I never got one, and that may be just as well. LOL My girlfriend and I did quite a few "science experiments" with household items, and are probably lucky we didn't blow the house up! Of course, we got started with the most common, safe, yet impressive reaction of vinegar and baking soda, then discovered that lemon juice also worked, but less dramatically.

      Later on, we would just throw random things together, a little of this; a little of that--no measuring-- to see what would happen. Our "test tubes" were glass cigar tubes someone had given me. I don't know what happened, chemically, on this one day, but we had mixed some liquid fish fertilizer, bleach, some of my mother's perfume, and I don't recall if there were other ingredients or not. The mixture sort of steamed/smoked, and the test tube got too hot to handle, and we dropped it into the mayo jar we were using as a rack. Naturally, the glass tube broke, and at that point, the steaming stopped. Coincidence? I'll never know.

      Wow! "That was pretty cool!" we thought, and our next thought was to wonder if we could replicate it. We were not able to do so through several attempts. "End" result: painful sitting for a few hours for having swiped mom's Chanel #5. ... ...

      As I moved on through school, I quickly learned I do not have the math-brain needed for pursuit of science of any kind. Nonetheless, it fascinates me still.

      Your article kicked up my "why?" gene. For example, why would you use/need specific colors of litmus paper? And how would you know which to use, if you are trying to find out what the property of the substance in the first place? What would happen if you used the opposite colors of paper?

      It surprises me that bleach is a base--considering its burning smell, and the damage it can do, I would have thought it was acidic. Learn something new every day!

      Voted up, interesting, useful and shared.

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