At the beginning.
If you mean with HubPages, I'd check out some of the other's articles. Check out subjects you are interested in and when you feel inspired, start writing. Don't worry if you do not have great articles at first, part of the point is to learn HOW to create great articles as you go. Write what is meaningful to you.
Visit the learning centre to learn all you need to know about the site:
As this is in the webdesign section I assume OP means with web design.
In which case I start with a site I like and look at the code.
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